A.1
Linear algebra reference
Vector spaces, inner products, eigenvalues, diagonalisation and tensor products — all in quantum mechanics' own notation, so you can look things up and head straight back to the main text.
Recommended first
- High-school vectors and complex arithmetic
After this section you should be able to
- Translate "states are vectors, observables are Hermitian operators" into concrete matrix computations
- Find the eigenvalues and eigenvectors of a 2×2 Hermitian matrix and carry out the diagonalisation
- Compute the tensor product of two small systems and read the subscripts of a many-body state
This section is a reference table doubling as a remedial station. If a word like “eigenvalue”, “unitary” or “tensor product” stops you in the main text, come here, find the matching subsection, read the minimum necessary explanation plus one worked example, and go back to reading. All notation follows the quantum-mechanical conventions ( rather than a column vector ), so any result you look up can be carried back into the main text verbatim.
Where the main text needs this: the whole of Chapter 3 is built on this language; 5.3 Spin 1/2 and 9.1 Qubits are the home turf of 2×2 matrices; 8.1 Identical particles and 9.3 Entanglement cannot do without tensor products.
Vector spaces and inner products
A vector space is, plainly put, “a set plus two rules”: the elements of the set (here called state vectors ) can be added together and multiplied by complex numbers, and the result stays inside the set. The superposition principle of quantum mechanics — a superposition of two allowed states is still an allowed state — is at bottom the statement that “states form a vector space”.
An inner product is a rule assigning a complex number to every pair of vectors; it measures how much two states “resemble” each other. Three properties are required:
| Property | Formula | In plain words |
|---|---|---|
| Conjugate symmetry | Swapping the order means taking the complex conjugate | |
| Linear in the right slot | Linear in the second argument | |
| Positive definite | , with equality only for | The inner product of a state with itself is its “length squared” |
Mind the second row: the physics convention is linear on the right, conjugate-linear on the left () — the opposite of most mathematics textbooks.
Two consequences you will use constantly:
This inequality is the mathematical backbone of the uncertainty principle. The normalisation condition corresponds to total probability 1.
Orthonormal basis: a set satisfying . Any state can be expanded as , with coefficients read off directly from inner products: . Abstracted into a single identity, this is the completeness relation
— “inserting a complete basis anywhere changes nothing”, the single most frequently used move in Chapter 3.
The eigenvalue problem
A matrix acting on a generic vector both rotates and stretches it. But every matrix has some “special directions”: acting along them produces pure stretching, no change of direction. These directions are the eigenvectors, and the stretch factors are the eigenvalues:
Finding them takes two steps:
- Eigenvalues: solve the characteristic equation . An -dimensional matrix gives a degree- polynomial with roots.
- Eigenvectors: substitute each back into and solve the linear system.
For 2×2 matrices there is a handy shortcut: the eigenvalues sum to the trace (sum of diagonal entries), and their product equals the determinant:
Worked example: eigenvalues and eigenvectors of σ_xbasic~5 min
The Pauli matrix plays the lead role in spin measurement.
Eigenvalues: , , so and , giving at once. (Or grind through the honest way.)
Eigenvectors: for the equation gives , and after normalisation
Likewise gives . Check orthogonality: . ✓
This is exactly the result that keeps reappearing in the main text: measuring spin along , the eigenstates are equal-weight superpositions of and .
Hermitian and unitary matrices
First define the Hermitian conjugate (symbol , read “dagger”): transpose the matrix, then complex-conjugate every entry, . It satisfies — the order reverses.
| Type | Definition | Physical role | Key properties |
|---|---|---|---|
| Hermitian | Observables | All eigenvalues real; eigenvectors of distinct eigenvalues mutually orthogonal | |
| Unitary | Time evolution, change of basis, quantum gates | Preserves inner products ; eigenvalues are unit-modulus complex numbers | |
| Projector | Measurement | Eigenvalues are only 0 and 1 |
The first two are linked by the exponential map: if is Hermitian, then is unitary — which is why the solution of the Schrödinger equation automatically conserves probability.
Two core theorems about Hermitian matrices (proofs in section 3.5):
- Eigenvalues must be real — so measurement outcomes are real numbers.
- Spectral theorem: a Hermitian matrix always admits an orthonormal set of eigenvectors forming a complete basis.
Diagonalisation and spectral decomposition
Diagonalising a matrix means switching to the basis made of its eigenvectors — in that basis the matrix becomes diagonal and all its information sits in plain view. Concretely: stack the normalised eigenvectors as the columns of a matrix (for a Hermitian matrix, is automatically unitary); then
An equivalent way to write it is the spectral decomposition — splitting the matrix into a sum of “eigenvalue × corresponding projector”:
Its greatest use is defining functions of a matrix: just apply the function eigenvalue by eigenvalue,
For instance — that single line is the entire mathematical content of the standard routine “expand in energy eigenstates, then attach a phase to each term”.
Tensor products
When two systems A and B combine into one larger system, the big system’s state space is not a “concatenation” but a tensor product : the dimensions multiply (), and the basis consists of all pairings (often abbreviated ).
The tensor (Kronecker) product of matrices expands as “each entry of the left matrix times the whole right matrix”:
The operating rule in one phrase: each factor minds its own system — . “Act on system A only” is written .
Worked example: write down a Bell state and show it cannot factoriseadvanced~4 min
In the two-qubit basis , take
Suppose it could be written as a product state ; expanding gives the four components . We need the middle two to vanish and the outer two not to: forces or , yet demands and demands — contradiction.
So is not a product of any two single-particle states: that is the definition of an entangled state, discussed in detail in section 9.3.
Key formulas
Completeness relation
License to "insert a complete basis" — Chapter 3's all-purpose tool
Eigenvalue problem
2×2 shortcut: eigenvalues sum to the trace, multiply to the determinant
Spectral decomposition
How matrix functions are defined; the time-evolution operator comes from here
Hermitian and unitary
Observables / evolution and change of basis; e^{-iHt/ħ} ties the two together
Tensor product
Dimensions multiply; states that cannot be factorised are called entangled
Self-check3 questions
- 1.
What are the two eigenvalues of the matrix A = [[3, 1], [1, 3]]?
- 2.
Which of the following is NOT true of a unitary matrix U?
- 3.
A system of three spin-1/2 particles has a state space of what dimension?
Section 99 of 106 · use ← → to turn the page